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14517aam a2200505 i 4500 001 4627DD6072D911EDA0B05B7C49ECA4DB 003 SILO 005 20221203010154 008 160608s2017 flua b 001 0 eng 010 $a 2016025947 020 $a 1498737617 020 $a 9781498737616 035 $a (OCoLC)951557354 040 $a DLC $b eng $e rda $c DLC $d OCLCO $d OCLCQ $d OCLCF $d YDXCP $d BTCTA $d BDX $d WAU $d YDX $d OCLCO $d CHVBK $d OCLCO $d CSAIL $d SILO 042 $a pcc 050 00 $a QD381 $b .C37 2017 082 00 $a 547/.7 $2 23 100 1 $a Carraher, Charles E., $c Jr., $d 1941- $e author. 245 10 $a Introduction to polymer chemistry / $c Charles E. Carraher, Jr. 250 $a Fourth edition. 264 1 $a Boca Raton, FL : $b CRC Press, $c [2017] 300 $a xxvii, 560 pages ; $c 29 cm 504 $a Includes bibliographical references and index. 505 00 $a Machine generated contents note: $g 3.3^ $t Theoretical Approaches to Solubility -- $g 1.2. $t Why Polymers? -- $g 1.3. $t Today's Marketplace -- $g 1.4. $t Environmental Assessment -- $g 1.4.1. $t Environmental Impact Assessment -- $g 1.4.2. $t Ecological Footprint -- $g 1.4.3. $t Life Cycle Assessment -- $g 1.5. $t Managing Sustainability -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $t General Encyclopedias and Dictionaries -- $g 2.1. $t Stereochemistry of Polymers -- $g 2.2. $t Molecular Interactions -- $g 2.2.1. $t Glass Transition and Melt Transition -- $g 2.2.2. $t Secondary Structures -- $g 2.3. $t Polymer Crystals -- $g 2.4. $t Amorphous Bulk State -- $g 2.5. $t Polymer Structure-Property Relationships -- $g 2.6. $t Crystalline and Amorphous Combinations -- $g 2.7. $t Cross-Linking -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 3.1. $t Introduction -- $g 3.2. $t Solubility -- $g 3.2.1. $t Basic Concepts -- $g 3.2.2. $t Theoretical Approaches to Solubility -- $g 3.3^ 505 00 $9 ^ $t Cellulose-Regenerating Processes -- $g 4.3.1^ $t Fractionation of Polydisperse Systems -- $g 3.5. $t Chromatography -- $g 3.5.1. $t General Chromatography -- $g 3.5.2. $t lon-Exchange Chromatography -- $g 3.5.3. $t Affinity Chromatography -- $g 3.5.4. $t High-Performance Liquid Chromatography -- $g 3.5.5. $t Electrophoresis -- $g 3.5.6. $t Gel Permeation Chromatography -- $g 3.5.7. $t Size Exclusion Chromatography -- $g 3.6. $t Colligative Molecular Weights -- $g 3.6.1. $t Osmometry -- $g 3.6.2. $t End-Group Analysis -- $g 3.6.3. $t Ebulliometry and Cryometry -- $g 3.7. $t Light-Scattering Photometry -- $g 3.8. $t Other Techniques -- $g 3.8.1. $t Ultracentrifugation -- $g 3.8.2. $t Mass Spectrometry -- $g 3.9. $t Viscometry -- $g 3.9.1. $t Solution Viscosity -- $g 3.9.2. $t Melted Polymer Viscosities -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 4.1. $t Polysaccharides -- $g 4.2. $t Cellulose -- $g 4.2.1. $t Paper -- $g 4.2.2. $t Paper Recycling -- $g 4.3. $t Cellulose-Regenerating Processes -- $g 4.3.1^ 505 00 $9 ^ $t Flow of Biological Information -- $g 4.8.3^1^ $t Wrinkle-Free Fabric -- $g 4.4. $t Esters and Ethers of Cellulose -- $g 4.4.1. $t Inorganic Esters -- $g 4.4.2. $t Organic Esters -- $g 4.4.3. $t Organic Ethers -- $g 4.5. $t Starch -- $g 4.6. $t Other Polysaccharides -- $g 4.6.1. $t Glycogen -- $g 4.6.2. $t Dextrans -- $g 4.6.3. $t Chitin -- $g 4.6.4. $t Chitosan -- $g 4.6.5. $t Heparin -- $g 4.6.6. $t Hyaluronic Acid -- $g 4.6.7. $t Chondroitin Sulfates -- $g 4.6.8. $t Arabinogalactans -- $g 4.6.9. $t Carrageenans, Agar, and Agarose -- $g 4.7. $t Proteins -- $g 4.7.1. $t Basics -- $g 4.7.2. $t Primary Structure -- $g 4.7.3. $t Secondary Structure -- $g 4.7.3.1. $t Keratins -- $g 4.7.3.2. $t Silk -- $g 4.7.3.3. $t Wool -- $g 4.7.4. $t Tertiary Structure -- $g 4.7.4.1. $t Globular Proteins -- $g 4.7.4.2. $t Fibrous Proteins -- $g 4.7.4.3. $t Elastin -- $g 4.7.4.4. $t Membrane Proteins -- $g 4.7.5. $t Quaternary Structure -- $g 4.8. $t Nucleic Acids -- $g 4.8.1. $t Basics -- $g 4.8.2. $t Flow of Biological Information -- $g 4.8.3^1^ 505 00 $9 ^ $t Liquid Crystals -- $g 5.17^ $t Naturally Occurring Polyisoprenes and Other Synthetic Elastomers -- $g 4.9.1. $t Balloons -- $g 4.9.2. $t Resins -- $g 4.9.3. $t Rosin and Related Materials -- $g 4.10. $t Lignin -- $g 4.11. $t Melanins -- $g 4.12. $t Polymer Structure -- $g 4.13. $t Genetic Engineering -- $g 4.14. $t DNA Profiling -- $g 4.15. $t Asphalt -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 5.1. $t Comparison between Polymer Type and Kinetics of Polymerization -- $g 5.2. $t Introduction -- $g 5.3. $t Stepwise Kinetics -- $g 5.4. $t Polycondensation Mechanisms -- $g 5.5. $t Polyesters and Polycarbonates -- $g 5.6. $t Synthetic Polyamides -- $g 5.7. $t Polymides -- $g 5.8. $t Polybenzimidazoles and Related Polymers -- $g 5.9. $t Polyurethanes and Polyureas -- $g 5.10. $t Polysulfides -- $g 5.11. $t Polyethers -- $g 5.12. $t Polysulfones -- $g 5.13. $t Poly(Ether Ether Ketone) and Polyketones -- $g 5.14. $t Phenolic and Amino Plastics -- $g 5.15. $t Synthetic Routes -- $g 5.16. $t Liquid Crystals -- $g 5.17^ 505 00 $9 ^ $t Medium-Density Polyethylene^^^ $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 6.6.8. $t Cationic Polymerization -- $g 6.1.1. $t Kinetics of Cationic Polymerization -- $g 6.1.2. $t Poly(Vinyl Isobutyl Ether) -- $g 6.1.3. $t Polyoxymethylene -- $g 6.1.4. $t Poly(Ethylene Oxide) -- $g 6.1.5. $t Polyterpenes and Related Polymers -- $g 6.2. $t Anionic Polymerization -- $g 6.2.1. $t Kinetics of Anionic Polymerization -- $g 6.2.2. $t Cis-1,4-Polyisoprene -- $g 6.2.3. $t Living Polymers -- $g 6.3. $t Stereoregularity and Stereogeometry -- $g 6.4. $t Polymerization with Complex Coordination Catalysts -- $g 6.5. $t Soluble Stereoregulating Catalysis -- $g 6.6. $t Polyethylenes -- $g 6.6.1. $t Introduction Polyethylenes -- $g 6.6.2. $t High-Density Polyethylene -- $g 6.6.3. $t Linear Low-Density Polyethylene -- $g 6.6.4. $t Very-Low-Density Polyethylene -- $g 6.6.5. $t Ultrahigh-Molecular-Weight Polyethylene -- $g 6.6.6. $t Ultralinear Polyethylene -- $g 6.6.7. $t Cross-Linked Polyethylene -- $g 6.6.8. $t Medium-Density Polyethylene^^^ 505 00 $9 ^ $g 7.4.4^ensity Polyethylene^^^ $t Solution Polymerization -- $g 6.6.10. $t Shopping Bags -- $g 6.7. $t Polypropylene -- $g 6.7.1. $t History -- $g 6.7.2. $t Stereospecific Structures -- $g 6.7.3. $t Early Production -- $g 6.7.4. $t Forms of Polypropylene -- $g 6.8. $t Polymers from 1,4-Dienes -- $g 6.8.1. $t Introduction -- $g 6.8.2. $t Butadiene Rubber -- $g 6.8.3. $t ABS -- $g 6.8.4. $t High-Impact Polystyrene -- $g 6.8.5. $t Polyisoprene -- $g 6.8.6. $t Polychloroprene -- $g 6.9. $t Polyisobutylene -- $g 6.10. $t Metathesis Reactions -- $g 6.11. $t Zwitterionic Polymerization -- $g 6.12. $t Isomerization Polymerization -- $g 6.13. $t Precipitation Polymerization -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 7.1. $t Initiators for Free Radical Chain Polymerization -- $g 7.2. $t Mechanism for Free Radical Chain Polymerization -- $g 7.3. $t Chain Transfer -- $g 7.4. $t Polymerization Techniques -- $g 7.4.1. $t Bulk Polymerization -- $g 7.4.2. $t Suspension Polymerization -- $g 7.4.3. $t Solution Polymerization -- $g 7.4.4^ensity Polyethylene^^^ 505 00 $9 ^ $t Miscible Blends -- $g 7.4.4^ensity Polyethylene^^^ $t Fluorine-Containing Polymers -- $g 7.5.1. $t Polytetrafluoroethylene -- $g 7.5.2. $t Poly(Vinyl Fluoride) -- $g 7.5.3. $t Other Fluorine-Containing Polymers -- $g 7.6. $t Polystyrene -- $g 7.7. $t Poly(Vinyl Chloride) -- $g 7.8. $t Poly(Methyl Methacrylate) -- $g 7.9. $t Polyacrylonitrile -- $g 7.10. $t Solid-State Irradiation Polymerization -- $g 7.11. $t Plasma Polymerizations -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 8.1. $t Kinetics of Copolymerization -- $g 8.2. $t The Q-e Scheme -- $g 8.3. $t Commercial Copolymers -- $g 8.4. $t Block Copolymers -- $g 8.5. $t Graft Copolymers -- $g 8.6. $t Elastomers -- $g 8.6.1. $t General -- $g 8.6.2. $t Thermoplastic Elastomers -- $g 8.6.3. $t SBR Copolymers -- $g 8.6.4. $t Sales and Flammability -- $g 8.7. $t Blends -- $g 8.7.1. $t General -- $g 8.7.2. $t Immiscible Blends -- $g 8.7.3. $t Immiscible Blends: Remainder of the Section on Immiscible Blends -- $g 8.7.4. $t Miscible Blends -- $g 8.8^-- $g 7.4.4^ensity Polyethylene^^^ 505 00 $9 ^ $t Aerogels -- $g 7.4.4^ensity Polyethylene^^^ $t Dendrites -- $g 8.10. $t lonomers -- $g 8.11. $t Fluoroelastomers -- $g 8.12. $t Nitrile Rubber -- $g 8.12.1. $t Laboratory Gloves -- $g 8.13. $t Acrylonitrile Butadiene Styrene Terpolymers -- $g 8.14. $t EPDM Rubber -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 9.1. $t Introduction -- $g 9.2. $t Inorganic Reaction Mechanisms -- $g 9.3. $t Condensation Organometallic Polymers -- $g 9.4. $t Coordination Polymers -- $g 9.5. $t Addition Polymers -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 10.1. $t Introduction -- $g 10.2. $t Portland Cement -- $g 10.3. $t Other Cements -- $g 10.4. $t Silicates -- $g 10.4.1. $t Network -- $g 10.4.2. $t Layer -- $g 10.4.3. $t Chain -- $g 10.5. $t Silicon Dioxide (Amorphous) -- $g 10.5.1. $t Kinds of Glass -- $g 10.5.2. $t Safety Glass -- $g 10.5.3. $t New Applications of Glass -- $g 10.5.4. $t Seeing Glass Lenses -- $g 10.6. $t Sol-Gel -- $g 10.6.1. $t Aerogels -- $g 10.7^ $g 8.8^-- $g 7.4.4^ensity Polyethylene^^^ 505 00 $9 ^ $t Zeolites^^^e^^^ $g 10.20. $t Silicon Dioxide in Electronic Chips -- $g 10.9. $t Asbestos -- $g 10.10. $t Fly Ash and Aluminosilicates -- $g 10.11. $t Polymeric Carbon: Diamond -- $g 10.12. $t Polymeric Carbon: Graphite -- $g 10.13. $t Internal Cyclization: Carbon Fibers and Related Materials -- $g 10.14. $t Carbon Nanotubes -- $g 10.14.1. $t General -- $g 10.14.2. $t Structures -- $g 10.14.3. $t Properties -- $g 10.14.3.1. $t Electrical -- $g 10.14.3.2. $t Mechanical -- $g 10.14.3.3. $t Field Emission -- $g 10.14.3.4. $t Hydrogen and Ion Storage -- $g 10.14.3.5. $t Chemical and Genetic Probes -- $g 10.14.3.6. $t Analytical Tools -- $g 10.14.3.7. $t Superconductors -- $g 10.14.4. $t Health Issues -- $g 10.14.5. $t Potential -- $g 10.15. $t Bitumens -- $g 10.16. $t Carbon Black -- $g 10.17. $t Polysulfur -- $g 10.18. $t Ceramics -- $g 10.19. $t High Temperature Superconductors -- $g 10.19.1. $t Discovery of the 123-Compound -- $g 10.19.2. $t Structure of the 123-Compound -- $g 10.20. $t Zeolites^^^e^^^ 505 00 $9 ^ $t Electron Paramagnetic Resonance Spectroscopy -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 12.1.6^tes^^^e^^^ $t Reactions with Polyolefins and Polyenes -- $g 11.2. $t Reactions of Aromatic and Aliphatic Pendant Groups -- $g 11.3. $t Degradation -- $g 11.4. $t Cross-Linking -- $g 11.5. $t Reactivities of End Groups -- $g 11.6. $t Supramolecules and Self-Assembly -- $g 11.7. $t Transfer and Retention of Oxygen -- $g 11.8. $t Nature's Macromolecular Catalysts -- $g 11.9. $t Photosynthesis -- $g 11.9.1. $t General -- $g 11.9.2. $t Purple Photosynthetic Bacteria -- $g 11.9.3. $t Green Sulfur Bacteria -- $g 11.10. $t Mechanisms of Physical Energy Absorption -- $g 11.11. $t Breakage of Polymeric Materials -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 12.1. $t Spectronic Characterization of Polymers -- $g 12.1.1. $t Infrared Spectroscopy -- $g 12.1.2. $t Raman Spectroscopy -- $g 12.1.3. $t Nuclear Magnetic Resonance Spectroscopy -- $g 12.1.4. $t NMR Applications -- $g 12.1.5. $t Electron Paramagnetic Resonance Spectroscopy -- $g 12.1.6^tes^^^e^^^ 505 00 $9 ^ $t Superresolution Fluorescence Microscopy $g 12.2.7. $t Surface Characterization -- $g 12.2.1. $t Attenuated Total Reflectance -- $g 12.2.2. $t Auger Electron Spectroscopy and X-Ray Photoelectron Spectroscopy -- $g 12.2.3. $t Near-Field Scanning Optical Microscopy -- $g 12.2.4. $t Electron Microscopy -- $g 12.2.5. $t Scanning Probe Microscopy -- $g 12.2.6. $t Secondary Ion Mass Spectroscopy -- $g 12.2.7. $t Superresolution Fluorescence Microscopy 505 00 $a Note continued: $g 13.4.4. $t Failure^^^ $g 12.4. $t Thermal Analysis -- $g 12.5. $t Thermal Property Tests -- $g 12.5.1. $t Thermal Conductivity -- $g 12.5.2. $t Thermal Expansion -- $g 12.5.3. $t Glass Transition Temperatures -- $g 12.6. $t Flammability -- $g 12.7. $t Electrical Properties: Theory -- $g 12.8. $t Electric Measurements -- $g 12.9. $t Weatherability -- $g 12.10. $t Optical Property Tests -- $g 12.10.1. $t Index of Refraction -- $g 12.10.2. $t Optical Clarity -- $g 12.10.3. $t Absorption and Reflectance -- $g 12.11. $t Chemical Resistance -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 13.1. $t Rheology -- $g 13.1.1. $t Rheology and Physical Tests -- $g 13.1.2. $t Response Time -- $g 13.2. $t Typical Stress-Strain Behavior -- $g 13.3. $t Stress-Strain Relationships -- $g 13.4. $t Specific Physical Tests -- $g 13.4.1. $t Tensile Strength -- $g 13.4.2. $t Tensile Strength of Inorganic and Metallic Fibers and Whiskers -- $g 13.4.3. $t Hardness -- $g 13.4.4. $t Failure^^^ 505 00 $9 ^ $t Polymer Processing^^^ $t Glossary -- $t Exercises -- $t Further Reading -- $g 16.1. $t Fillers -- $g 14.2. $t Reinforcements -- $g 14.2.1. $t Fibers and Resins -- $g 14.2.2. $t Applications -- $g 14.3. $t Nanocomposites -- $g 14.4. $t Plasticizers -- $g 14.5. $t Antioxidants -- $g 14.6. $t Heat Stabilizers -- $g 14.7. $t Ultraviolet Stabilizers -- $g 14.8. $t Flame Retardants -- $g 14.9. $t Colorants -- $g 14.10. $t Curing Agents -- $g 14.11. $t Antistatic Agents: Antistats -- $g 14.12. $t Chemical Blowing Agents -- $g 14.13. $t Compatibilizers -- $g 14.14. $t Impact Modifiers -- $g 14.15. $t Processing Aids -- $g 14.16. $t Lubricants -- $g 14.17. $t Microorganism Inhibitors -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 15.1. $t Monomer Synthesis from Basic Feedstocks -- $g 15.2. $t Reactants for Step-Reaction Polymerization -- $g 15.3. $t Synthesis of Vinyl Monomers -- $g 15.4. $t Search for Less Expensive Feedstocks -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading -- $g 16.1. $t Polymer Processing^^^ 505 00 $9 ^ $g 16.9.1^^^^ $t Extrusion -- $g 16.1.2. $t Secondary Structures: Mesophases -- $g 16.2. $t Fibers -- $g 16.2.1. $t Polymer Processing: Spinning and Fiber Production -- $g 16.2.1.1. $t Introduction -- $g 16.2.1.2. $t Melt Spinning -- $g 16.2.1.3. $t Dry Spinning -- $g 16.2.1.4. $t Wet Spinning -- $g 16.3. $t Elastomers -- $g 16.3.1. $t Elastomer Processing -- $g 16.4. $t Films and Sheets -- $g 16.4.1. $t Calendering -- $g 16.5. $t Polymeric Foams -- $g 16.6. $t Reinforced Plastics (Composites) and Laminates -- $g 16.6.1. $t Composites -- $g 16.6.2. $t Particle-Reinforced Composites: Large-Particle Composites -- $g 16.6.3. $t Fiber-Reinforced Composites -- $g 16.6.4. $t Processing of Fiber-Reinforced Composites -- $g 16.6.5. $t Structural Composites -- $g 16.6.6. $t Laminating -- $g 16.7. $t Molding -- $g 16.7.1. $t Injection Molding -- $g 16.7.2. $t Blow Molding -- $g 16.7.3. $t Rotational Molding -- $g 16.7.4. $t Compression and Transfer Molding -- $g 16.7.5. $t Thermoforming -- $g 16.8. $t Casting -- $g 16.9. $t Extrusion -- $g 16.9.1^^^^ 505 00 $9 ^ $t Further Reading. $g 16.17. $t Rainwear -- $g 16.10. $t Coatings -- $g 16.11. $t Adhesives -- $g 16.12. $t Conductive Polymeric Materials -- $g 16.12.1. $t Photoconductive and Photonic Polymers -- $g 16.12.2. $t Electrically Conductive Polymers -- $g 16.13. $t Drug Design and Activity -- $g 16.14. $t Synthetic Biomedical Polymers -- $g 16.15. $t Dental Materials -- $g 16.16. $t Emerging Polymers -- $g 16.17. $t Green Materials -- $t Summary -- $t Glossary -- $t Exercises -- $t Further Reading. 650 0 $a Polymers. 650 0 $a Polymerization. 941 $a 2 952 $l PQAX094 $d 20231214021627.0 952 $l PLAX964 $d 20230718092750.0 956 $a http://locator.silo.lib.ia.us/search.cgi?index_0=id&term_0=4627DD6072D911EDA0B05B7C49ECA4DB 994 $a Z0 $b IOWInitiate Another SILO Locator Search