3.3.3.1. 1. Mechanism: alkalinity, saponification and metal dissolution 1.1. Why corrosion-protective coatings -- 1.2. Literature -- 2. Corrosion protection coatings -- 2.1. Principles of function -- 2.1.1. Electrochemistry of corrosion inhibition -- 2.1.2. Metal Oxide Formation -- 2.1.3. Cathodic protection -- 2.1.4. Passivation and conversion coating -- 2.2. Design of organic coating systems -- 2.2.1. Diffusion barrier features-humidity uptake and electrolyte permeation -- 2.2.2. Active pigments -- 2.3. Function of individual coating layers -- 2.4. Literature -- 3. Surface preparation -- 3.1. Industrial cleaning -- 3.1.1. Importance of cleaning process -- 3.1.2. Contaminants -- 3.1.3. Surface energy and tension -- 3.2. Mechanical cleaning -- 3.3. Chemical cleaning -- 3.3.1. Plasma and corona processes -- 3.3.2. Solvent cleaning -- 3.3.3. Chemistry of aqueous cleaners -- 3.3.3.1. Mechanism: alkalinity, saponification and metal dissolution 4.2.8. Polyaspartics 3.3.3.2.1. General considerations -- 3.3.3.2.2. Surfactants -- 3.3.4. Physics of aqueous cleaning, bath life and rinsing -- 3.4. Literature -- 4. Organic coating materials -- 4.1. Ingredients of organic coating materials -- 4.2. Resins -- 4.2.1. Alkyd resins -- 4.2.1.1. Alkyd resins manufacturing process -- 4.2.1.2. Decay of alkyd resins -- 4.2.1.3. Composition of alkyd resins -- 4.2.1.4. Curing of alkyd resins -- 4.2.2. Chlorinated rubber -- 4.2.3. Polyvinyl chloride -- 4.2.4. Epoxy resins -- 4.2.4.1. Raw materials for epoxy resins -- 4.2.4.2. Manufacturing process for epoxy resins -- 4.2.4.3. Cross-linking of the epoxy resins -- 4.2.5. Epoxy esters -- 4.2.6. Acrylic resins -- 4.2.6.1. Manufacturing of acrylic resins -- 4.2.6.2. Thermoplastic and thermosetting acrylic resins -- 4.2.7. Polyurethanes -- 4.2.7.1. Reactivity of isocyanate group -- 4.2.7.2. Waterborne polyurethanes -- 4.2.7.3. Isocyanate free polyurethanes -- 4.2.8. Polyaspartics 4.3.1.9. Zinc cyanamide 4.2.8.2. Polyaspartic systems -- 4.2.9.1. Nomenclature of the silicon chemistry -- 4.2.9.2. Manufacturing of alkyl silicates -- 4.2.9.3. Reactions of alkyl silicates -- 4.2.10. Polysiloxanes -- 4.2.10.1. Reactions of siloxanes -- 4.2.10.2. Manufacturing of siloxanes -- 4.3. Pigments-Introduction -- 4.3.1. Corrosion protection pigments -- 4.3.1.1. Lead and chromate pigments -- 4.3.1.1.1. Lead pigments -- 4.3.1.1.2. Chromate pigments -- 4.3.1.2. Phosphate based pigments -- 4.3.1.2.1. Zinc phosphate -- 4.3.1.2.2. Modified orthophosphates -- 4.3.1.2.3. Modified polyphosphates -- 4.3.1.3. Inorganic/organic synergies -- 4.3.1.4. Wide spectrum anticorrosives -- 4.3.1.5. Phosphites and phosphides -- 4.3.1.5.1. Zinc hydroxyphosphite -- 4.3.1.5.2. Iron phosphide -- 4.3.1.6. Borates -- 4.3.1.6.1. Barium metaborate -- 4.3.1.6.2. Zinc borate -- 4.3.1.6.3. Calcium borosilicate -- 4.3.1.7. Molybdates -- 4.3.1.8. Ion-exchange pigments -- 4.3.1.9. Zinc cyanamide 5.2.2.2. Applications 4.3.2. Barrier pigments -- 4.3.2.1. Micaceous iron oxide -- 4.3.2.2. Aluminium flakes -- 4.3.2.3. Zinc flakes -- 4.3.3. Sacrificial pigments -- 4.3.3.1. Zinc dust -- 4.3.3.2. Magnesium -- 4.3.4. Colouring agent -- 4.3.4.1. White pigment, titanium dioxide -- 4.3.4.2. Red pigments -- 4.3.4.3. Yellow pigments -- 4.3.4.4. Green pigments -- 4.3.4.5. Blue pigments -- 4.3.4.6. Black pigments -- 4.4. Extender pigments -- 4.4.1. Carbonates -- 4.4.2. Sulphates -- 4.4.3. Silicas -- 4.4.4. Silicates -- 4.4.4.1. Talc -- 4.4.4.2. Kaolin -- 4.4.4.3. Wollastonite -- 4.4.4.4. Mica -- 4.5. Other additives -- 4.6. Solvents -- 4.7. Raw materials for powder coatings -- 4.8. Literature -- 5. Film formation -- 5.1. Physical drying -- 5.2. Chemical curing -- 5.2.1. Thermal cross-linking: chemistry, mechanism, imparted properties -- 5.2.2. Radiation curing -- 5.2.2.1. Chemical principles and intrinsic properties -- 5.2.2.2. Applications 6.6.2.2. Anodic disbonding: filiform corrosion 5.3. Literature -- 6. Mechanism of protection and properties of organic coatings -- 6.1. Measurement of physical properties and influence -- 6.2. Dry film thickness -- 6.3. Adhesiveness -- 6.3.1. Role of adhesion and factors of influence -- 6.3.2. Measurement of adhesion and elasticity -- 6.3.2.1. Industrial methods -- 6.3.2.2. Laboratory methods -- 6.4. Permeation through organic coatings -- 6.5. Corrosion protective performance -- 6.5.1. Titanium and zirconium fluoro complex based pretreatments -- 6.5.2. Weldable corrosion protection primer for automotive sheet -- 6.5.3. Thermally curing 2-in-1 primer-pretreatment -- 6.5.4. Chromous based pretreatments-chromiting -- 6.5.5. Active pigments, ion exchangers and scavengers -- 6.5.6. UV-curable primer-pretreatment -- 6.6. Degradation and ageing -- 6.6.1. Weathering -- 6.6.2. Electrochemical degradation -- 6.6.2.1. Cathodic disbonding: oxygen reduction -- 6.6.2.2. Anodic disbonding: filiform corrosion 8. Chemical conversion treatment 7. Testing of organic coatings -- 7.1. Performance testing -- 7.2. Accelerated corrosion tests -- 7.2.1. Overview -- 7.2.2. Constant climate tests -- 7.2.2.1. Salt spray -- 7.2.2.2. Constant climate, humidity -- 7.2.2.3. Filiform corrosion -- 7.2.2.4. Condensation -- 7.2.2.5. Boiling, water soak -- 7.2.3. Cyclic climate tests -- 7.2.3.1. Cyclic humidity -- 7.2.3.2. Prohesion -- 7.2.3.3. VDA test -- 7.2.3.4. UV test, weathering -- 7.3. Electrochemical testing -- 7.3.1. General remarks -- 7.3.2. Electrochemical potential -- 7.3.2.1. Standard potential -- 7.3.2.2. Cyclovoltammetry -- 7.3.3. Electrochemical impedance spectroscopy -- 7.3.4. Electrochemical techniques with high spatial resolution -- 7.3.4.1. Scanning vibrating electrode -- 7.3.4.2. Height-regulated Scanning Kelvin Probe -- 7.3.4.2.1. General technique -- 7.3.4.2.2. Blister test -- 7.4. Outdoor exposure tests -- 7.5. Literature -- 8. Chemical conversion treatment 9.1.1. General considerations 8.2. Chemicals for pretreatment -- 8.2.1. General remarks -- 8.2.2. Alkaline passivation -- 8.2.3. Phosphating -- 8.2.3.1. Iron phosphating -- 8.2.3.2. Zinc phosphating -- 8.2.4. Chromating -- 8.2.5. Anodising of aluminium -- 8.2.6. Chromiting -- 8.2.7. Chromium-free pretreatment -- 8.2.7.1. Titanium and zirconium fluoro-complex technology -- 8.2.7.2. Other chromium-free pretreatments -- 8.2.8. Hybrid pretreatment coatings -- 8.2.8.1. Silane/siloxane coatings -- 8.2.8.2. Combined thermal processes for primer-pretreatment -- 8.2.9. Surface preparation of other substrates-copper alloys, white metal, magnesium, stainless steel -- 8.2.10. Environmental considerations -- 8.3. Application of pretreatments -- 8.3.1. Immersion and Spray Treatment -- 8.3.2. Pretreatment application for coil: spray/squeeze, spray-cell, roll-coating -- 8.4. Literature -- 9. Organic coatings for maintenance -- 9.1. Surface tolerant coatings -- 9.1.1. General considerations 11.4. Literature. 9.2. Organic coatings on residual rust and old coatings -- 9.3. Literature -- 10. New corrosion protection concepts -- 10.1. Thin films -- 10.1.1. Self-assembling monolayers -- 10.1.2. Conducting polymers -- 10.1.3. Biopolymers -- 10.2. Nanomaterials -- 10.2.1. Nanocomposites -- 10.2.2. Sol-gel derived ceramic and hybrid coatings -- 10.3. Self-healing coatings -- 10.3.1. Self-repairing polymer films -- 10.3.2. Inhibitor release -- 10.4. Conclusions -- 10.5. Literature -- 11. Standards and guidelines -- 11.1. General information -- 11.2. General norms -- 11.2.1. Norms on mechanical testing of organically coated metallic work pieces -- 11.2.2. Norms on corrosion testing of organically coated metallic work pieces -- 11.3. Selected European legislation on environmental protection -- 11.4. Literature.
Summary:
"An interdisciplinary guide to organic coatings and their use on different types of material, with a strong focus on metals that are most prone to corrosion."--pub. desc.
This resource is supported by the Institute of Museum and Library Services under the provisions of the Library Services and Technology Act as administered by State Library of Iowa.