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Author:

Yang, Jaemoon.

Title:

Six-membered transition states in organic synthesis / Jaemoon Yang.

Publisher:

Wiley-Interscience,

Copyright Date:

c2008

Description:

x, 210 p. : ill. ; 25 cm.

Subject:

Reaction mechanisms (Chemistry)
Stereochemistry.
Organic compounds--Synthesis.

Notes:

Includes bibliographical references and indexes.

Contents:

[3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction -- Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction -- Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction -- Stereoselective reductions. Diastereoselective syn-reduction of [beta]-hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction.

Summary:

This book presents a comprehensive overview of six-membered chair-like transition states in organic synthesis. Logically organized by reaction type, the sections focus on [3,3]-sigmatropic rearrangements, aldol reactions, metal allylation reactions, stereoselective reductions, and other reactions. Each reaction contains an introduction to the reaction type and history, a discussion of the corresponding six-membered chair-like transition state, and details of synthetic applications in natural products synthesis.

ISBN:

0470178833
9780470178836

OCLC:

(OCoLC)126230993

LCCN:

2007019896

Locations:

USUX851 -- Iowa State University - Parks Library (Ames)

OZAX845 -- Northwestern College - DeWitt Library (Orange City)