Revised edition of: Chemical and engineering thermodynamics. Includes bibliographical references and index.
Contents:
Machine generated contents note: Instructional Objectives for Chapter 1 -- Important Notation Introduced in This Chapter -- 1.1.The Central Problems of Thermodynamics -- 1.2.A System of Units -- 1.3.The Equilibrium State -- 1.4.Pressure, Temperature, and Equilibrium -- 1.5.Heat, Work, and the Conservation of Energy -- 1.6.Specification of the Equilibrium State; Intensive and Extensive Variables; Equations of State -- 1.7.A Summary of Important Experimental Observations -- 1.8.A Comment on the Development of Thermodynamics -- Problems -- Instructional Objectives for Chapter 2 -- Important Notation Introduced in This Chapter -- 2.1.A General Balance Equation and Conserved Quantities -- 2.2.Conservation of Mass for a Pure Fluid -- 2.3.The Mass Balance Equations for a Multicomponent System with a Chemical Reaction -- 2.4.The Microscopic Mass Balance Equations in Thermodynamics and Fluid Mechanics (Optional -- only on the website for this book) -- Problems -- Note continued: Instructional Objectives for Chapter 3 -- Notation Introduced in This Chapter -- 3.1.Conservation of Energy -- 3.2.Several Examples of Using the Energy Balance -- 3.3.The Thermodynamic Properties of Matter -- 3.4.Applications of the Mass and Energy Balances -- 3.5.Conservation of Momentum -- 3.6.The Microscopic Energy Balance (Optional -- only on website for this book) -- Problems -- Instructional Objectives for Chapter 4 -- Notation Introduced in This Chapter -- 4.1.Entropy: A New Concept -- 4.2.The Entropy Balance and Reversibility -- 4.3.Heat, Work, Engines, and Entropy -- 4.4.Entropy Changes of Matter -- 4.5.Applications of the Entropy Balance -- 4.6.Availability and the Maximum Useful Shaft Work that can be obtained In a Change of State -- 4.7.The Microscopic Entropy Balance (Optional -- only on website for this book) -- Problems -- Instructional Objectives for Chapter 5 -- Notation Introduced in this Chapter -- 5.1.Liquefaction -- Note continued: 5.2.Power Generation and Refrigeration Cycles -- 5.3.Thermodynamic Efficiencies -- 5.4.The Thermodynamics of Mechanical Explosions -- Problems -- Instructional Objectives for Chapter 6 -- Notation Introduced in this Chapter -- 6.1.Some Mathematical Preliminaries -- 6.2.The Evaluation of Thermodynamic Partial Derivatives -- 6.3.The Ideal Gas and Absolute Temperature Scales -- 6.4.The Evaluation of Changes in the Thermodynamic Properties of Real Substances Accompanying a Change of State -- 6.5.An Example Involving the Change of State of a Real Gas -- 6.6.The Principle of Corresponding States -- 6.7.Generalized Equations of State -- 6.8.The Third Law of Thermodynamics -- 6.9.Estimation Methods for Critical and Other Properties -- 6.10.Sonic Velocity -- 6.11.More About Thermodynamic Partial Derivatives (Optional -- only on website for this book) -- Problems -- Instructional Objectives for Chapter 7 -- Notation Introduced in This Chapter -- Note continued: 7.1.The Criteria for Equilibrium -- 7.2.Stability of Thermodynamic Systems -- 7.3.Phase Equilibria: Application of the Equilibrium and Stability Criteria to the Equation of State -- 7.4.The Molar Gibbs Energy and Fugacity of a Pure Component -- 7.5.The Calculation of Pure Fluid-Phase Equilibrium: The Computation of Vapor Pressure from an Equation of State -- 7.6.Specification of the Equilibrium Thermodynamic State of a System of Several Phases: The Gibbs Phase Rule for a One-Component System -- 7.7.Thermodynamic Properties of Phase Transitions -- 7.8.Thermodynamic Properties of Small Systems, or Why Subcooling and Superheating Occur -- Problems -- Instructional Objectives for Chapter 8 -- Notation Introduced in This Chapter -- 8.1.The Thermodynamic Description of Mixtures -- 8.2.The Partial Molar Gibbs Energy and the Generalized Gibbs-Duhem Equation -- 8.3.A Notation for Chemical Reactions -- 8.4.The Equations of Change for a Multicomponent System -- Note continued: 8.5.The Heat of Reaction and a Convention for the Thermodynamic Properties of Reacting Mixtures -- 8.6.The Experimental Determination of the Partial Molar Volume and Enthalpy -- 8.7.Criteria for Phase Equilibrium in Multicomponent Systems -- 8.8.Criteria for Chemical Equilibrium, and Combined Chemical and Phase Equilibrium -- 8.9.Specification of the Equilibrium Thermodynamic State of a Multicomponent, Multiphase System; the Gibbs Phase Rule -- 8.10.A Concluding Remark -- Problems -- Instructional Objectives for Chapter 9 -- Notation Introduced in This Chapter -- 9.1.The Ideal Gas Mixture -- 9.2.The Partial Molar Gibbs Energy and Fugacity -- 9.3.Ideal Mixture and Excess Mixture Properties -- 9.4.Fugacity of Species in Gaseous, Liquid, and Solid Mixtures -- 9.5.Several Correlative Liquid Mixture Activity Coefficient Models -- 9.6.Two Predictive Activity Coefficient Models -- 9.7.Fugacity of Species in Nonsimple Mixtures -- Note continued: 9.8.Some Comments on Reference and Standard States -- 9.9.Combined Equation-of-State and Excess Gibbs Energy Model -- 9.10.Electrolyte Solutions -- 9.11.Choosing the Appropriate Thermodynamic Model -- Appendix A9.1 A Statistical Mechanical Interpretation of the Entropy of Mixing in an Ideal Mixture (Optional -- only on the website for this book) -- Appendix A9.2 Multicomponent Excess Gibbs Energy (Activity Coefficient) Models -- Appendix A9.3 The Activity Coefficient of a Solvent in an Electrolyte Solution -- Problems -- Instructional Objectives for Chapter 10 -- Notation Introduced in This Chapter -- 10.0.Introduction to Vapor-Liquid Equilibrium -- 10.1.Vapor-Liquid Equilibrium in Ideal Mixtures -- Problems for Section 10.1 -- 10.2.Low-Pressure Vapor-Liquid Equilibrium in Nonideal Mixtures -- Problems for Section 10.2 -- 10.3.High-Pressure Vapor-Liquid Equilibria Using Equations of State (0-0 Method) -- Problems for Section 10.3 -- Note continued: Instructional Objectives for Chapter 11 -- Notation Introduced in This Chapter -- 11.1.The Solubility of a Gas in a Liquid -- Problems for Section 11.1 -- 11.2.Liquid-Liquid Equilibrium -- Problems for Section 11.2 -- 11.3.Vapor-Liquid-Liquid Equilibrium -- Problems for Section 11.3 -- 11.4.The Partitioning of a Solute Among Two Coexisting Liquid Phases; The Distribution Coefficient -- Problems for Section 11.4 -- 11.5.Osmotic Equilibrium and Osmotic Pressure -- Problems for Section 11.5 -- Instructional Objectives for Chapter 12 -- Notation Introduced in This Chapter -- 12.1.The Solubility of a Solid in a Liquid, Gas, or Supercritical Fluid -- Problems for Section 12.1 -- 12.2.Partitioning of a Solid Solute Between Two Liquid Phases -- Problems for Section 12.2 -- 12.3.Freezing-Point Depression of a Solvent Due to the Presence of a Solute; the Freezing Point of Liquid Mixtures -- Problems for Section 12.3 -- 12.4.Phase Behavior of Solid Mixtures -- Note continued: Problems for Section 12.4 -- 12.5.The Phase Behavior Modeling of Chemicals in the Environment -- Problems for Section 12.5 -- 12.6.Process Design and Product Design -- Problems for Section 12.6 -- 12.7.Concluding Remarks on Phase Equilibria -- Instructional Objectives for Chapter 13 -- Important Notation Introduced in This Chapter -- 13.1.Chemical Equilibrium in a Single-Phase System -- 13.2.Heterogeneous Chemical Reactions -- 13.3.Chemical Equilibrium When Several Reactions Occur in a Single Phase -- 13.4.Combined Chemical and Phase Equilibrium -- 13.5.Ionization and the Acidity of Solutions -- 13.6.Ionization of Biochemicals -- 13.7.Partitioning of Amino Acids and Proteins Between Two Liquids -- Problems -- Instructional Objectives for Chapter 14 -- Notation Introduced in This Chapter -- 14.1.The Balance Equations for a Tank-Type Chemical Reactor -- 14.2.The Balance Equations for a Tubular Reactor -- Note continued: 14.3.Overall Reactor Balance Equations and the Adiabatic Reaction Temperature -- 14.4.Thermodynamics of Chemical Explosions -- 14.5.Maximum Useful Work and Availability in Chemically Reacting Systems -- 14.6.Introduction to Electrochemical Processes -- 14.7.Fuel Cells and Batteries -- Problems -- Instructional Objectives for Chapter 15 -- Notation Introduced in This Chapter -- 15.1.Solubilities of Weak Acids, Weak Bases, and Amino Acids as a Function of pH -- 15.2.The Solubility of Amino Acids and Proteins as a function of Ionic Strength and Temperature -- 15.3.Binding of a Ligand to a Substrate -- 15.4.Some Other Examples of Biochemical Reactions -- 15.5.The Denaturation of Proteins -- 15.6.Coupled Biochemical Reactions: The ATP-ADP Energy Storage and Delivery Mechanism -- 15.7.Thermodynamic Analysis of Fermenters and Other Bioreactors -- 15.8.Gibbs-Donnan Equilibrium and Membrane Potentials -- 15.9.Protein Concentration in an Ultracentrifuge -- Note continued: Problems -- Appendix A.I Conversion Factors For Si Units -- Appendix A.II The Molar Heat Capacities Of Gases In The Ideal Gas (Zero Pressure) State -- Appendix A.III The Thermodynamic Properties Of Water And Steam -- Appendix A.IV Enthalpies And Free Energies Of Formation -- Appendix A.V Heats Of Combustion -- Appendix B.I Windows-Based Visual Basic Programs -- Appendix B.II Dos-Based Basic Programs -- Appendix B.III Mathcad Worksheets -- Appendix B.IV Matlab Programs.
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